⚠️ Affiliate Disclosure: This post contains affiliate links. We may earn a commission if you purchase through our links, at no extra cost to you. We only recommend products we've thoroughly researched.

AHA vs BHA vs PHA: Key Differences

TypeBest Skin TypeWorks OnStrengthSun Sensitivity
AHA (glycolic, lactic)Dry, dull, matureSurface texture, dark spotsMedium–StrongHigh — always use SPF
BHA (salicylic)Oily, acne-proneInside pores, blackheadsMediumModerate
PHA (gluconolactone)Sensitive, drySurface, gentle brighteningMildLow

Alpha Hydroxy Acids (AHAs)

AHAs are water-soluble acids that dissolve the "glue" holding dead skin cells together on the surface. They're derived from natural sources: glycolic acid from sugarcane, lactic acid from milk, mandelic acid from almonds.

Glycolic Acid

Smallest molecule → deepest penetration → most powerful results. Best for: texture, fine lines, hyperpigmentation. Start at 5–8% and work up to 10–12%.

Lactic Acid

Gentler than glycolic with a larger molecule size. Also a humectant, so it hydrates while it exfoliates. Best for: dry skin, beginners, sensitive types. 5–10% is effective.

Mandelic Acid

Largest AHA molecule, slowest penetration, gentlest effect. Also antibacterial, making it surprisingly effective for acne-prone skin. Best for: combination skin, melasma, sensitive skin that can't tolerate glycolic.

Best AHA Toner

Paula's Choice Skin Perfecting 8% AHA Gel Exfoliant

★★★★★ 4.6/5

Glycolic acid at an effective 8% concentration in a gentle, leave-on gel formula. One of the most consistent exfoliants in the industry with decades of research behind it.

Check Price on Amazon →

Beta Hydroxy Acids (BHAs)

The only BHA used in skincare is salicylic acid. Unlike AHAs, salicylic acid is oil-soluble — meaning it can penetrate through the sebum in your pores to dissolve blackheads and whiteheads from the inside out. This makes it uniquely effective for acne-prone skin.

Best BHA Product

Paula's Choice Skin Perfecting 2% BHA Liquid Exfoliant

★★★★★ 4.7/5 (19,000+ reviews)

The #1 recommended BHA by dermatologists worldwide. Salicylic acid at 2% in a lightweight leave-on formula. Visibly reduces blackheads, smooths bumpy texture, and controls shine.

Check Price on Amazon →

Polyhydroxy Acids (PHAs)

PHAs are the newest and gentlest category. Their larger molecular size means slower, more superficial penetration — which means less irritation. They're perfect for beginners, sensitive skin, and anyone who finds AHAs too harsh.

Common PHAs: gluconolactone, lactobionic acid, galactose. Bonus: they're also antioxidants and humectants.

How to Build a Safe Exfoliation Routine

Week 1–2: Use 1x per week in the evening only. Apply to clean, dry skin. Moisturize after. Use SPF the next morning (AHAs especially increase photosensitivity).

Week 3–4: Increase to 2x per week if no irritation. Watch for redness, excessive flaking, or tightness — these signal over-exfoliation, not progress.

Month 2+: Settle into 3–4x per week or as your skin tolerates. Never exfoliate on the same evening as retinol or vitamin C (with strong AHAs).

⚠️ Over-Exfoliation Warning: The most common mistake. If your skin is shiny, feels tight, stings with everything you apply, or is suddenly breaking out, you've damaged your skin barrier. Stop all exfoliation for 2 weeks and focus on barrier repair (ceramides, niacinamide, hyaluronic acid).

Frequently Asked Questions

How often should you use a chemical exfoliant?
Beginners: 1–2x per week. With experience, 3–4x per week is fine for most people. PHAs can be used daily. Daily AHA/BHA use is only appropriate at very low concentrations and after building significant tolerance.
Should you use AHA or BHA for acne?
BHA (salicylic acid) first — it's oil-soluble and clears inside pores where acne starts. Add an AHA for surface texture, post-acne marks, and overall skin tone improvement. Many people use BHA 3–4x/week and AHA 1–2x/week.
Can I use a chemical exfoliant with retinol?
Not on the same night — both are resurfacing agents and the combination significantly increases irritation risk. Use exfoliant on Monday/Wednesday/Friday nights; use retinol on Tuesday/Thursday/Saturday nights.

Related Articles

Read Next
Glycolic Acid Toner Guide
Read Next
Salicylic Acid Guide
Read Next
Retinol Percentage Guide
Read Next
Azelaic Acid Guide
SC

Dr. Sarah Chen, Dermatologist

Board-certified dermatologist with 12+ years experience. Contributor to major skincare publications and advisor to several clean beauty brands. Dr. Chen specializes in ingredient science and evidence-based skincare.